Publication Details:

"ՀՀ ԳԱԱ Զեկույցներ" հանդեսը հիմնադրվել է 1944թ.: Լույս է տեսնում տարին 4 անգամ, 2026-ից՝ 2 անգամ։

Journal or Publication Title:

ՀՀ ԳԱԱ Զեկույցներ = Доклады НАН РА = Reports NAS RA

Date of publication:

2026

Volume:

126

Number:

2

ISSN:

0321-1339 ; e-3045-3151

Official URL:

Additional Information:

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Contributor(s):

Պատ․ խմբ.՝ Վ. Հ․ Համբարձումյան (1944-1959) ; Մ․ Մ․ Ջրբաշյան (1960-1965) ; Ա․ Գ․ Նազարով (1966-1983) ; Պատ․ խմբ․ տեղակալ՝ Վ․ Հ․ Ղազարյան (1983-1986) ; Պատ․ խմբ․՝ Դ․ Մ․ Սեդրակյան (1987-1999) ; Գլխավոր խմբ․՝ Ս․ Ա․ Համբարձումյան (2000-2004) ; Վ․ Ս․ Զաքարյան (2005-2018) ; Ռ․ Մ․ Մարտիրոսյան (2018-2025) ; Ա․ Ս․ Սաղյան (2026-)

Coverage:

1-23

Abstract:

Furanic molecules obtained by dehydration and upgrading of carbohydrates have become a central chemical language for translating renewable biomass into fuels, polymers, solvents, ionic liquids, pharmaceuticals, adsorbents and aromatic building blocks. Yet the field has reached a stage at which the word 'platform' is no longer sufficient. The current frontier is not simply the preparation of 5-(hydroxymethyl)furfural (HMF), furfural (FF), 2,5-diformylfuran (DFF), 2,5-bis(hydroxymethyl)furan (BHMF) or 2,5-furandicarboxylic acid (FDCA), but the disciplined design of carbon-efficient sequences in which feedstock variability, product instability, separations, toxicity, catalytic durability and end-of-life chemistry are treated as one connected problem. This review develops this unified approach around green furanics after the HMF bottleneck. The literature selected herein is used as a core scaffold for discussion of carbohydrate-to-HMF chemistry, HMF aging and stability, electrochemical and catalytic oxidation, hydrogenation and hydrodeoxygenation, Diels-Alder furan-to-aromatics chemistry, C-H functionalization, materials, antimicrobial and adsorption applications, humins valorization and biodegradation. Placing these studies in a broader contemporary landscape – encompassing HMF electrooxidation, paired electrolysis, PEF scale-up, earth-abundant catalysis, furan-core editing, and circular materials – highlights the next decisive challenges. The review argues that the next decisive advances will come from treating HMF not as a molecule to be isolated at any cost, but as a node in adaptive reaction networks where the best intermediate is selected by stability, reactivity, separation and product function.

Place of publishing:

Երևան

Publisher:

ՀՀ ԳԱԱ հրատ.

Format:

pdf

Identifier:

oai:arar.sci.am:440953

Call number:

АЖ 144

Digitization:

ՀՀ ԳԱԱ Հիմնարար գիտական գրադարան

Location of original object:

ՀՀ ԳԱԱ Հիմնարար գիտական գրադարան