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Armenian Journal of Physics=Ֆիզիկայի հայկական հանդես
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M. A. Kazaryan ; I. V. Shamanin
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Abstract:
In experiments [1,2] the phenomenon of induced selective drift of cationic aquacomplexes in water solutions of salts under action of asymmetric electric fields which frequency does not exceed tens of kilohertz was revealed. In this case the grid electrodes placed in a solution and forming the field have been isolated from the solution, and the current through the border between a solution and an electrode was absent. Action of a variable magnetic field on the water solution of salt also excited intensive mass-transport. Experimental data and theoretical estimations [3] have shown that excitation of rotary-onward motions of solvated cations (clusters) with various inertial properties can become a basis for technology of separation of rare earth elements in water solutions of their salts. The further theoretical and experimental researches have demanded to use new not-contradicting and complementary approximations, and specify existence of new applications of solvation process of ions in solutions of salts in liquid polar dielectrics. As it was clarified the conditions providing use of solvation process for the decision of various applied problems, first of all are determined by the sizes of solvated ions (clusters). In the present work we carry out the generalization of results of researches which have been directed on studying of relations between these conditions and properties of clusters.